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81.
Ohne Zusammenfassung Der Deutschen Forschungsgemeinschaft sei für die Unterstützung der Arbeit gedankt.  相似文献   
82.
Chemical interactions between 2-aminobenzothiazole (ABT) and a soil humic acid (HA) extracted from a gleyic planosol were investigated by solid-state 13C CP/MAS NMR spectroscopy. Reactions of the HA with ABT 13C-labelled at the C-2 position were performed in aqueous solution under noncatalysed and enzyme-catalysed conditions. Without enzymic catalysis the amount of ABT-2-13C taken up by soil HA in an oxygen atmosphere was about twice the uptake under argon. In the presence of the oxidative enzyme laccase and air, about three times as much ABT was bound to HA as compared to the uptake in a control experiment with inactivated laccase. The results suggest that oxidation reactions of the humic acid significantly enhance the extent of binding between ABT and HA. The 13C NMR spectra of the HA–ABT adducts indicated that in both noncatalysed and enzyme-catalysed reactions ABT may be bound to humic acid by noncovalent as well as covalent bonds.  相似文献   
83.
Geochemistry of Peruvian near-surface sediments   总被引:6,自引:0,他引:6  
Sixteen short sediment cores were recovered from the upper edge (UEO), within (WO) and below (BO) the oxygen minimum zone (OMZ) off Peru during cruise 147 of R/V Sonne. Solids were analyzed for major/trace elements, total organic carbon, total inorganic carbon, total sulfur, the stable sulfur isotope composition (δ34S) of pyrite, and sulfate reduction rates (SRR). Pore waters were analyzed for dissolved sulfate/sulfide and δ34S of sulfate. In all cores highest SRR were observed in the top 5 cm where pore water sulfate concentrations varied little due to resupply of sulfate by sulfide oxidation and/or diffusion of sulfate from bottom water. δ34S of dissolved sulfate showed only minor downcore increases. Strong 32S enrichments in sedimentary pyrite (to −48‰ vs. V-CDT) are due to processes in the oxidative part of the sulfur cycle in addition to sulfate reduction. Manganese and Co are significantly depleted in Peruvian upwelling sediments most likely due to mobilization from particles settling through the OMZ, whereas release of both elements from reducing sediments only seems to occur in near-coastal sites. Cadmium, Mo and Re are exceptionally enriched in WO sediments (<600 m water depth). High Re and moderate Cd and Mo enrichments are seen in BO sediments (>600 m water depth). Re/Mo ratios indicate anoxic and suboxic conditions for WO and BO sediments, respectively. Cadmium and Mo downcore profiles suggest considerable contribution to UEO/WO sediments by a biodetrital phase, whereas Re presumably accumulates via diffusion across the sediment-water interface to precipitation depth. Uranium is distinctly enriched in WO sediments (due to sulfidic conditions) and in some BO sediments (due to phosphorites). Silver transfer to suboxic BO sediments is likely governed by diatomaceous matter input, whereas in anoxic WO sediments Ag is presumably trapped due to sulfide precipitation. Cadmium, Cu, Zn, Ni, Cr, Ag, and T1 predominantly accumulate via biogenic pre-concentration in plankton remains. Rhenium, Sb, As, V, U and Mo are enriched in accordance with seawater TE availability. Lead and Bi enrichment in UEO surface sediments is likely contributed by anthropogenic activity (mining). Accumulation rates of TOC, Cd, Mo, U, and V from Peruvian and Namibian sediments exceed those from the Oman Margin and Gulf of California due to enhanced preservation off Peru and Namibia.  相似文献   
84.
85.
This report summarizes the seismicity in Switzerland and surrounding regions in the years 2015 and 2016. In 2015, the Swiss Seismological Service detected and located 735 earthquakes in the region under consideration. With a total of 20 earthquakes of magnitude ML ≥ 2.5, the seismic activity of potentially felt events in 2015 was close to the average of 23 earthquakes over the previous 40 years. Seismic activity was above average in 2016 with 872 located earthquakes of which 31 events had ML ≥ 2.5. The strongest event in the analyzed period was the ML 4.1 Salgesch earthquake, which occurred northeast of Sierre (VS) in October 2016. The event was felt in large parts of Switzerland and had a maximum intensity of V. Derived focal mechanisms and relative hypocenter relocations of aftershocks image a SSE dipping reverse fault, which likely also hosted an ML 3.9 earthquake in 2003. Another remarkable earthquake sequence in the Valais occurred close to Sion with four felt events (ML 2.7–3.2) in 2015/16. We associate this sequence with a system of WNW-ESE striking fault segments north of the Rhône valley. Similarities with a sequence in 2011, which was located about 10 km to the NE, suggest the existence of an en-echelon system of basement faults accommodating dextral slip along the Rhône-Simplon line in this area. Another exceptional earthquake sequence occurred close to Singen (Germany) in November 2016. Relocated hypocenters and focal mechanisms image a SW dipping transtensional fault segment, which is likely associated with a branch of the Hegau-Bodensee Graben. On the western boundary of this graben, micro-earthquakes close to Schlattingen (TG) in 2015/16 are possibly related to a NE dipping branch of the Neuhausen Fault. Other cases of earthquakes felt by the public during 2015/16 include earthquakes in the region of Biel, Vallorcine, Solothurn, and Savognin.  相似文献   
86.
87.
The Upper Pleistocene geoarchives in the south-eastern Carpathian Basin are represented predominantly by loess–palaeosol records. In 2015, a 10 m sediment core composed of clay-rich lacustrine sediments was recovered by vibracoring a dry lake basin located between the Vršac Mountains (Serbia) and the Banat Sands in the south-eastern Carpathian Basin; a location relevant for placing regional archaeological results in a palaeoenvironmental context. Here, we present results from geoelectrical prospection and a lithostratigraphic interpretation of this sequence supported by a detailed granulometric study supplemented by ostracod analysis. An age model based on luminescence dating is discussed against sedimentological proxy data and its implication for palaeoenvironmental change. The cores show a stratigraphy of lighter ochre-coloured and darker greyish sediment, related to the deposition of clay and silt trapped in an aquatic environment. Geophysical measurements show ~20 m thick lacustrine sediments. The grain-size distributions including the variability in fine clay are indicative of a lacustrine environment. Fine particles were brought into the depositional environments by aquatic input and settled from suspension; also, direct dust input is constrained by grain-size results. Riverine input and aeolian dust input interplayed at the locality.  相似文献   
88.
A provenance and stratigraphic study of the Neoproterozoic Pontas do Salso Complex (PSC), western portion of the Dom Feliciano Belt (DFB), was conducted with U–Pb zircon geochronological analysis of the metasediments and the host rocks. The U–Pb isotopic data from detrital zircon of the metasediments indicate the source from the latest Middle Tonian to Late Cryogenian (between 897 and 684 Ma) and maximum depositional age of 685 ± 18 Ma in an arc-related basin setting adjacent in the Sao Gabriel Arc. The metasediments of the PSC form an elongated body in the N35°E direction and occur in the central portion of the São Gabriel Terrane (SGT), which is constituted by ophiolitic complexes and arc-related rocks, generated probably during the final consolidation of Rodinia supercontinent, although this question is still open. Low- to medium-K calc-alkaline, metaluminous affinity, and trace-element geochemistry suggest that the chemical composition of the protoliths was generated from metasomatized mantle sources in subduction zones. The PSC is composed of meta-arkoses, with subordinate metaconglomerates and metapelites. The meta-arkoses are disposed in plane-parallel layers, which also internally feature small-scale cross-bedding structures. The matrix has a blastopsammitic, poorly selected, fine to coarse texture, and hexagonal quartz and plagioclase porphyroclasts with superimposed thermal metamorphism. The polymict metaconglomerates are matrix-supported, with 15–55% of clasts of metavolcanic rocks, metasediments, undeformed granites, and quartz veins. The metapelites comprise mainly muscovite phyllites with syn-tectonic garnet and chloritoid porphyroblasts. The PSC represents a sedimentary succession deposited on an arc-related basin formed during the collapse and uplift of the SGT.  相似文献   
89.
Lichens are now well known for their potential as bio-indicators of environmental pollution, but less is known about their suitability as quantitative biomonitors for atmospheric emissions of tritium (mainly as tritiated water, HTO) and radiocarbon (as 14CO2) from nuclear facilities, although both radionuclides could result in non-trivial individual or collective radiation doses due to their high environmental mobility and their long half-lives. 3H and 14C are fixed in lichens mainly by the photosynthesis of the algal partner and then stored in the organic molecules of both alga and fungus. They have the advantage of allowing the monitoring of atmospheric water vapour without interference of soil water or soil organic substances as long as soil-inhabiting species are avoided. Lichens were collected in the surroundings of (military and civil) nuclear facilities, in areas away from any direct source of contamination and some were transplanted from a contaminated area to a non-contaminated one. The influence of the nuclear facilities can be clearly traced, sometimes in a spectacular way and the first results of analyses after transplants give a base for estimating the effective half-life of 3H in lichens.  相似文献   
90.
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